Widespread natural perchlorate in unsaturated zones of the southwest United States

Balaji Rao, Todd A. Anderson, Greta J. Orris, Ken A. Rainwater, Srinath Rajagopalan, Renee M. Sandvig, Bridget R. Scanlon, David A. Stonestrom, Michelle A. Walvoord, W. Andrew Jackson

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Abstract

A substantial reservoir (up to 1 kg ha-1) of natural perchlorate is present in diverse unsaturated zones of the arid and semi-arid southwestern United States. The perchlorate co-occurs with meteoric chloride that has accumulated in these soils throughout the Holocene [0 to 10-15 ka (thousand years ago)] and possibly longer periods. Previously, natural perchlorate widely believed to be limited to the Atacama Desert, now appears widespread in steppe-to-desert ecoregions. The perchlorate reservoir becomes sufficiently large to affect groundwater when recharge from irrigation or climate change flushes accumulated salts from the unsaturated zone. This new source may help explain increasing reports of perchlorate in dry region agricultural products and should be considered when evaluating overall source contributions.

Original languageEnglish
Pages (from-to)4522-4528
Number of pages7
JournalEnvironmental Science and Technology
Volume41
Issue number13
DOIs
StatePublished - Jul 1 2007

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    Rao, B., Anderson, T. A., Orris, G. J., Rainwater, K. A., Rajagopalan, S., Sandvig, R. M., Scanlon, B. R., Stonestrom, D. A., Walvoord, M. A., & Jackson, W. A. (2007). Widespread natural perchlorate in unsaturated zones of the southwest United States. Environmental Science and Technology, 41(13), 4522-4528. https://doi.org/10.1021/es062853i