Vibrational deactivation of singlet methylene

W. L. Hase, R. J. Phillips, J. W. Simons

Research output: Contribution to journalArticle

39 Scopus citations

Abstract

CF4 and C8F18 collisionally remove excess energy, presumably vibrational, from CH2(1A1). Results from increasing proportions of C8F18 with CH2N2 and CH2CO precursors indicated that ΔHfo0[1CH2(1A1)] ≈ 101 kcal/mole. A simplified model indicates that 80-800 CF4 and 10-100 C8F18 collisions remove one bending vibrational quantum from CH2(1A1).

Original languageEnglish
Pages (from-to)161-165
Number of pages5
JournalChemical Physics Letters
Volume12
Issue number1
DOIs
StatePublished - Dec 1 1971

Fingerprint Dive into the research topics of 'Vibrational deactivation of singlet methylene'. Together they form a unique fingerprint.

  • Cite this