Vibrational deactivation of singlet methylene

W. L. Hase, R. J. Phillips, J. W. Simons

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

CF4 and C8F18 collisionally remove excess energy, presumably vibrational, from CH2(1A1). Results from increasing proportions of C8F18 with CH2N2 and CH2CO precursors indicated that ΔHfo0[1CH2(1A1)] ≈ 101 kcal/mole. A simplified model indicates that 80-800 CF4 and 10-100 C8F18 collisions remove one bending vibrational quantum from CH2(1A1).

Original languageEnglish
Pages (from-to)161-165
Number of pages5
JournalChemical Physics Letters
Volume12
Issue number1
DOIs
StatePublished - Dec 1 1971

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