Twisted oxygen-containing oligosilanes - Unprecedented examples of σ-n mixed conjugated systems

Clemens Krempner; Ralf Ludwig; Anke Flemming; Ralf Miethchen; Martin Köckerling

doi:10.1039/b618438c

Twisted oxygen-containing oligosilanes - Unprecedented examples of σ-n mixed conjugated systems

Clemens Krempner, Ralf Ludwig, Anke Flemming, Ralf Miethchen, Martin Köckerling

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Twisting the silicon backbone conformation in oxygen containing oligosilanes towards dihedral angles of 120-130° either by intramolecular hydrogen bonding or incorporation into a covalently bonded ring system effectively extends the delocalization of electrons in these σ-n mixed conjugated systems.

Original language	English
Pages (from-to)	1810-1812
Number of pages	3
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b618438c
State	Published - 2007

Access to Document

10.1039/b618438c

Cite this

@article{5718527feeeb47238dc457722155dd9c,

title = "Twisted oxygen-containing oligosilanes - Unprecedented examples of σ-n mixed conjugated systems",

abstract = "Twisting the silicon backbone conformation in oxygen containing oligosilanes towards dihedral angles of 120-130° either by intramolecular hydrogen bonding or incorporation into a covalently bonded ring system effectively extends the delocalization of electrons in these σ-n mixed conjugated systems.",

author = "Clemens Krempner and Ralf Ludwig and Anke Flemming and Ralf Miethchen and Martin K{\"o}ckerling",

year = "2007",

doi = "10.1039/b618438c",

language = "English",

pages = "1810--1812",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry (RSC)",

number = "18",

}

TY - JOUR

T1 - Twisted oxygen-containing oligosilanes - Unprecedented examples of σ-n mixed conjugated systems

AU - Krempner, Clemens

AU - Ludwig, Ralf

AU - Flemming, Anke

AU - Miethchen, Ralf

AU - Köckerling, Martin

PY - 2007

Y1 - 2007

N2 - Twisting the silicon backbone conformation in oxygen containing oligosilanes towards dihedral angles of 120-130° either by intramolecular hydrogen bonding or incorporation into a covalently bonded ring system effectively extends the delocalization of electrons in these σ-n mixed conjugated systems.

AB - Twisting the silicon backbone conformation in oxygen containing oligosilanes towards dihedral angles of 120-130° either by intramolecular hydrogen bonding or incorporation into a covalently bonded ring system effectively extends the delocalization of electrons in these σ-n mixed conjugated systems.

UR - http://www.scopus.com/inward/record.url?scp=34247882807&partnerID=8YFLogxK

U2 - 10.1039/b618438c

DO - 10.1039/b618438c

M3 - Article

AN - SCOPUS:34247882807

SN - 1359-7345

SP - 1810

EP - 1812

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Twisted oxygen-containing oligosilanes - Unprecedented examples of σ-n mixed conjugated systems

Abstract

Access to Document

Other files and links

Fingerprint

Cite this