Trajectory studies of unimolecular processes. II. Dynamics of chloroacetylene dissociation

William L. Hase, Da Fei Feng

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

Lifetime distributions for H-C≡C-Cl with respect to dissociation were determined at 200, 175, and 150 kcal/mole. Both random and nonrandom sampling techniques were used. An analysis of distributions of internal coordinate energies shows that vibrational energy redistribution is nearly complete within 4.5×10-13 sec. The results indicate that H-C≡C-Cl is an "intrinsic" RRKM molecule in the 200-150 kcal/mole energy domain.

Original languageEnglish
Pages (from-to)651-655
Number of pages5
JournalThe Journal of Chemical Physics
Volume64
Issue number2
DOIs
StatePublished - 1976

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