Thiophene-2-carbonyl azide

Gene C. Hsu, Laci Singer, David B. Cordes, Michael Findlater

Research output: Contribution to journalArticlepeer-review


The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC - H⋯N - =N + =NR interactions between an aromatic C - H group and an azide moiety which, in conjunction with a complementary C - H⋯O=C interaction, forms a nine-membered ring.
Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
StatePublished - Aug 1 2013


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