Thiophene-2-carbonyl azide

Gene C. Hsu, Laci M. Singer, David B. Cordes, Michael Findlater

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding interactions between adjacent molecules. Of particular note is the occurrence of RC - H⋯N -=N+=NR interactions between an aromatic C - H group and an azide moiety which, in conjunction with a complementary C - H⋯O=C interaction, forms a nine-membered ring.

Original languageEnglish
Pages (from-to)o1298
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number8
DOIs
StatePublished - Aug 2013

Keywords

  • Rfactor = 0.050
  • T = 153 K
  • data-to-parameter ratio = 16.0
  • meanω(C - C) = 0.004 A °
  • single-crystal X-ray study
  • wRfactor = 0.154

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