Thermosetting cure diagrams: Calculation and application

S. L. Simon; J. K. Gillham

doi:10.1002/app.1994.070530601

Thermosetting cure diagrams: Calculation and application

S. L. Simon, J. K. Gillham

Chemical Engineering

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57 Scopus citations

Abstract

The time–temperature–transformation (TTT) isothermal cure diagram and the continuous‐heating‐transformation (CHT) cure diagram are calculated from a reaction model for a high‐T_g epoxy/amine system that has been developed to describe both epoxy/amine and etherification reactions in kinetically and diffusion‐controlled reaction regimes. The cure diagrams are applied to various processing operations. The optimization of processing and of material properties by exploiting gelation and/or vitrification during cure is discussed. © 1994 John Wiley & Sons, Inc.

Original language	English
Pages (from-to)	709-727
Number of pages	19
Journal	Journal of Applied Polymer Science
Volume	53
Issue number	6
DOIs	https://doi.org/10.1002/app.1994.070530601
State	Published - Aug 8 1994

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title = "Thermosetting cure diagrams: Calculation and application",

abstract = "The time–temperature–transformation (TTT) isothermal cure diagram and the continuous‐heating‐transformation (CHT) cure diagram are calculated from a reaction model for a high‐Tg epoxy/amine system that has been developed to describe both epoxy/amine and etherification reactions in kinetically and diffusion‐controlled reaction regimes. The cure diagrams are applied to various processing operations. The optimization of processing and of material properties by exploiting gelation and/or vitrification during cure is discussed. {\textcopyright} 1994 John Wiley & Sons, Inc.",

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AB - The time–temperature–transformation (TTT) isothermal cure diagram and the continuous‐heating‐transformation (CHT) cure diagram are calculated from a reaction model for a high‐Tg epoxy/amine system that has been developed to describe both epoxy/amine and etherification reactions in kinetically and diffusion‐controlled reaction regimes. The cure diagrams are applied to various processing operations. The optimization of processing and of material properties by exploiting gelation and/or vitrification during cure is discussed. © 1994 John Wiley & Sons, Inc.

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ER -

Thermosetting cure diagrams: Calculation and application

Abstract

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