Thermodynamic representation of phase equilibria of mixed‐solvent electrolyte systems

Bill Mock; L. B. Evans; Chau‐Chyun ‐C Chen

doi:10.1002/aic.690321009

Thermodynamic representation of phase equilibria of mixed‐solvent electrolyte systems

Bill Mock, L. B. Evans, Chau‐Chyun ‐C Chen

Chemical Engineering

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353 Scopus citations

Abstract

The electrolyte nonrandom two‐liquid model proposed by Chen and Evans provides a thermodynamically consistent framework for representation of the phase equilibria of mixed‐solvent electrolyte systems. Using only binary adjustable parameters, the model satisfactorily correlates the vapor‐liquid equilibrium and liquid‐liquid equilibrium of mixed‐solvent electrolyte systems over the entire range of temperature and concentrations.

Original language	English
Pages (from-to)	1655-1664
Number of pages	10
Journal	AIChE Journal
Volume	32
Issue number	10
DOIs	https://doi.org/10.1002/aic.690321009
State	Published - Oct 1986

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abstract = "The electrolyte nonrandom two‐liquid model proposed by Chen and Evans provides a thermodynamically consistent framework for representation of the phase equilibria of mixed‐solvent electrolyte systems. Using only binary adjustable parameters, the model satisfactorily correlates the vapor‐liquid equilibrium and liquid‐liquid equilibrium of mixed‐solvent electrolyte systems over the entire range of temperature and concentrations.",

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AB - The electrolyte nonrandom two‐liquid model proposed by Chen and Evans provides a thermodynamically consistent framework for representation of the phase equilibria of mixed‐solvent electrolyte systems. Using only binary adjustable parameters, the model satisfactorily correlates the vapor‐liquid equilibrium and liquid‐liquid equilibrium of mixed‐solvent electrolyte systems over the entire range of temperature and concentrations.

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Thermodynamic representation of phase equilibria of mixed‐solvent electrolyte systems

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