The unusual UV absorption behavior of chloro functionalized oligosilane dendrimers

C. Krempner, H. Reinke

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

The unusual UV spectroscopic behavior of the chloro functionalized oligosilane dendrimers [R(Me3Si)2Si-Me2Si] 3Si-Cl (3a,b) derived from reactions of R(Me3Si) 2Si-K (2a,b) with Cl-Si(SiMe2Cl)3 (1) is reported (a; R = SiMe3 and b; R = Me). The dendritic silanol [Me(Me3Si)2Si][Me(Me3Si)2Si-Me 2Si]2Si-SiMe2OH (6) has been isolated as a side product and was characterized by X-ray structure analysis.

Original languageEnglish
Pages (from-to)259-262
Number of pages4
JournalInorganic Chemistry Communications
Volume9
Issue number3
DOIs
StatePublished - Mar 2006

Keywords

  • Clorosilanes
  • Dendrimers
  • Silanes
  • Silanols
  • Silicon

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