The synthesis and characterization of [IMesH] <sup>+</sup>[(η<sup>3</sup>-C<inf>5</inf>H<inf>5</inf>)V(N)Cl <inf>2</inf>]<sup>-</sup>: An anionic vanadium(v) complex with a terminal nitrido ligand

Carl E. Johnson, Everett A. Kysor, Michael Findlater, Jerry P. Jasinski, Andrew S. Metell, Jonathan W. Queen, Colin D. Abernethy

Research output: Contribution to journalArticlepeer-review

Abstract

A series of new half-sandwich vanadium complexes have been prepared. The structures of two new anionic vanadium half-sandwich complexes, [CpVCl 3 ] - and [CpV(N)Cl 2 ] - are presented. 15 N isotopic labelling studies have been conducted to unambiguously assign the VN infra red stretching frequencies of both a neutral and an anionic (cyclopentadienyl)vanadium nitrido complex. The influence of strongly π-basic coligands on the hapticity of the cyclopentadienyl ligands in half-sandwich complexes of vanadium is discussed. © 2010 The Royal Society of Chemistry.
Original languageEnglish
Pages (from-to)3482-3488
JournalDalton Transactions
StatePublished - Apr 29 2010

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