Abstract
A series of new half-sandwich vanadium complexes have been prepared. The structures of two new anionic vanadium half-sandwich complexes, [CpVCl 3]- and [CpV(N)Cl2]- are presented. 15N isotopic labelling studies have been conducted to unambiguously assign the VN infra red stretching frequencies of both a neutral and an anionic (cyclopentadienyl)vanadium nitrido complex. The influence of strongly π-basic coligands on the hapticity of the cyclopentadienyl ligands in half-sandwich complexes of vanadium is discussed.
Original language | English |
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Pages (from-to) | 3482-3488 |
Number of pages | 7 |
Journal | Dalton Transactions |
Volume | 39 |
Issue number | 14 |
DOIs | |
State | Published - 2010 |