TY - JOUR
T1 - The stereochemistry of migrated hopanes epimeric at C-21
AU - Nes, W. David
AU - Heupel, Rick C.
AU - Benson, Mabry
AU - Stafford, Allan E.
AU - Haddon, William F.
PY - 1984
Y1 - 1984
N2 - The structures of four migrated hopanes, isolated from Sorghum bicolor and epimeric at C-21 and/or enantiomeric at the C-8, C-13, C-14, C-17, C-18, and C-21 positions: fernenol, 21-epifernenol (trematol), isoarborinol, and 21-epi-isoarborinol (sorghumol, a previously unidentified pentacycle), have been determined by analysing the chromatographic (g.l.c. and h.p.l.c.), spectral (mass and 1H n.m.r.), and physical constant (m.p.) data of the naturally occurring (free) and chemically synthesized acetate and methyl ether derivatives.
AB - The structures of four migrated hopanes, isolated from Sorghum bicolor and epimeric at C-21 and/or enantiomeric at the C-8, C-13, C-14, C-17, C-18, and C-21 positions: fernenol, 21-epifernenol (trematol), isoarborinol, and 21-epi-isoarborinol (sorghumol, a previously unidentified pentacycle), have been determined by analysing the chromatographic (g.l.c. and h.p.l.c.), spectral (mass and 1H n.m.r.), and physical constant (m.p.) data of the naturally occurring (free) and chemically synthesized acetate and methyl ether derivatives.
UR - http://www.scopus.com/inward/record.url?scp=37049109386&partnerID=8YFLogxK
U2 - 10.1039/c39840000223
DO - 10.1039/c39840000223
M3 - Article
AN - SCOPUS:37049109386
SN - 0022-4936
SP - 223
EP - 225
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 4
ER -