Abstract
The C 1B2 state of SO2 has a double-minimum potential in the antisymmetric stretch coordinate, such that the minimum energy geometry has nonequivalent SO bond lengths. The asymmetry in the potential energy surface is expressed as a staggering in the energy levels of the ν3′ progression. We have recently made the first observation of low-lying levels with odd quanta of v3′, which allows us - in the current work - to characterize the origins of the level staggering. Our work demonstrates the usefulness of low-lying vibrational level structure, where the character of the wavefunctions can be relatively easily understood, to extract information about dynamically important potential energy surface crossings that occur at much higher energy. The measured staggering pattern is consistent with a vibronic coupling model for the double-minimum, which involves direct coupling to the bound 2 1A1 state and indirect coupling with the repulsive 3 1A1 state. The degree of staggering in the ν3′ levels increases with quanta of bending excitation, which is consistent with the approach along the C state potential energy surface to a conical intersection with the 2 1A1 surface at a bond angle of ∼145°.
Original language | English |
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Article number | 144313 |
Pages (from-to) | 144313 |
Journal | THE JOURNAL OF CHEMICAL PHYSICS |
Volume | 144 |
Issue number | 14 |
DOIs | |
State | Published - Apr 14 2016 |