The Formation and an Unusual Dimerization of 2‐Mesityl‐1,1‐bis(trimethylsilyl)silene

Clemens Krempner; Helmut Reinke; Hartmut Oehme

doi:10.1002/anie.199416151

The Formation and an Unusual Dimerization of 2‐Mesityl‐1,1‐bis(trimethylsilyl)silene

Clemens Krempner, Helmut Reinke, Hartmut Oehme

Chemistry and Biochemistry

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Abstract

A formal role as monoene and also as diene by utilizing the mesityl substituent is possible for the unstable silene 1. In the absence of scavengers, 1 dimerizes in an unusual [2 + 4] reaction to form 2 as soon as it is prepared from (Me₃Si)₃SiC(OH)Mes. (Figure Presented.)

Original language	English
Pages (from-to)	1615-1618
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	15-16
DOIs	https://doi.org/10.1002/anie.199416151
State	Published - Sep 2 1994

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title = "The Formation and an Unusual Dimerization of 2‐Mesityl‐1,1‐bis(trimethylsilyl)silene",

abstract = "A formal role as monoene and also as diene by utilizing the mesityl substituent is possible for the unstable silene 1. In the absence of scavengers, 1 dimerizes in an unusual [2 + 4] reaction to form 2 as soon as it is prepared from (Me3Si)3SiC(OH)Mes. (Figure Presented.)",

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AU - Reinke, Helmut

AU - Oehme, Hartmut

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AB - A formal role as monoene and also as diene by utilizing the mesityl substituent is possible for the unstable silene 1. In the absence of scavengers, 1 dimerizes in an unusual [2 + 4] reaction to form 2 as soon as it is prepared from (Me3Si)3SiC(OH)Mes. (Figure Presented.)

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The Formation and an Unusual Dimerization of 2‐Mesityl‐1,1‐bis(trimethylsilyl)silene

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