The Effect of Swelling on the Elasticity of Rubber: Localization Model Description

Jack F. Douglas; Gregory B. McKenna

doi:10.1021/ma00065a006

The Effect of Swelling on the Elasticity of Rubber: Localization Model Description

Jack F. Douglas, Gregory B. McKenna

Chemical Engineering

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24 Scopus citations

Abstract

The success of the localization model in describing the elasticity of unswollen natural rubber is reviewed and the model is extended to describe the elasticity of swollen networks. In contrast to the Frenkel-Flory-Rehner modeling of network elasticity, the localization model predicts that the mechanical response of swollen rubbers changes qualitatively in going from low to high cross-link densities. The implications of these predictions are discussed.

Original language	English
Pages (from-to)	3282-3288
Number of pages	7
Journal	Macromolecules
Volume	26
Issue number	13
DOIs	https://doi.org/10.1021/ma00065a006
State	Published - 1993

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title = "The Effect of Swelling on the Elasticity of Rubber: Localization Model Description",

abstract = "The success of the localization model in describing the elasticity of unswollen natural rubber is reviewed and the model is extended to describe the elasticity of swollen networks. In contrast to the Frenkel-Flory-Rehner modeling of network elasticity, the localization model predicts that the mechanical response of swollen rubbers changes qualitatively in going from low to high cross-link densities. The implications of these predictions are discussed.",

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AU - Douglas, Jack F.

AU - McKenna, Gregory B.

PY - 1993

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N2 - The success of the localization model in describing the elasticity of unswollen natural rubber is reviewed and the model is extended to describe the elasticity of swollen networks. In contrast to the Frenkel-Flory-Rehner modeling of network elasticity, the localization model predicts that the mechanical response of swollen rubbers changes qualitatively in going from low to high cross-link densities. The implications of these predictions are discussed.

AB - The success of the localization model in describing the elasticity of unswollen natural rubber is reviewed and the model is extended to describe the elasticity of swollen networks. In contrast to the Frenkel-Flory-Rehner modeling of network elasticity, the localization model predicts that the mechanical response of swollen rubbers changes qualitatively in going from low to high cross-link densities. The implications of these predictions are discussed.

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U2 - 10.1021/ma00065a006

DO - 10.1021/ma00065a006

M3 - Article

AN - SCOPUS:0027606674

VL - 26

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EP - 3288

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 13

ER -

The Effect of Swelling on the Elasticity of Rubber: Localization Model Description

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