Tetrakis(imino)pyracene complexes exhibiting multielectron redox processes

Kalyan V. Vasudevan, Michael Findlater, Ignacio Vargas-Baca, Alan H. Cowley

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

The differences in redox behavior of the monofunctional bis(imino)acenaphthene (BIAN) and bifunctional tetrakis(imino)pyracene (TIP) ligands have been explored by treatment of the latter with PI 3, TeI 4, or BI 3. These reactions result in the formation of products involving the transfer of three or four electrons. Accompanying DFT calculations reveal that in each case the extent of electron transfer from each p-block element into the TIP ligand is dependent upon the element-TIP bonding interactions.

Original languageEnglish
Pages (from-to)176-178
Number of pages3
JournalJournal of the American Chemical Society
Volume134
Issue number1
DOIs
StatePublished - Jan 11 2012

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