Tert-butyl N-(thiophen-2-yl)carbamate

Gene C. Hsu; Laci Singer; David B. Cordes; Michael Findlater

Tert-butyl N-(thiophen-2-yl)carbamate

Gene C. Hsu, Laci Singer, David B. Cordes, Michael Findlater

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C 9 H 13 NO 2 S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°] . An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin. © 2013 Hsu et al.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
State	Published - Sep 1 2013

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title = "Tert-butyl N-(thiophen-2-yl)carbamate",

abstract = "In the title compound, C 9 H 13 NO 2 S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°] . An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin. {\textcopyright} 2013 Hsu et al.",

author = "Hsu, {Gene C.} and Laci Singer and Cordes, {David B.} and Michael Findlater",

year = "2013",

month = sep,

day = "1",

language = "English",

journal = "Acta Crystallographica Section E: Structure Reports Online",

}

TY - JOUR

T1 - Tert-butyl N-(thiophen-2-yl)carbamate

AU - Hsu, Gene C.

AU - Singer, Laci

AU - Cordes, David B.

AU - Findlater, Michael

PY - 2013/9/1

Y1 - 2013/9/1

N2 - In the title compound, C 9 H 13 NO 2 S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°] . An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin. © 2013 Hsu et al.

AB - In the title compound, C 9 H 13 NO 2 S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°] . An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin. © 2013 Hsu et al.

M3 - Article

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -