Tert-butyl N-(thiophen-2-yl)carbamate

Gene C. Hsu; Laci M. Singer; David B. Cordes; Michael Findlater

doi:10.1107/S160053681302196X

Tert-butyl N-(thiophen-2-yl)carbamate

Gene C. Hsu, Laci M. Singer, David B. Cordes, Michael Findlater

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In the title compound, C₉H₁₃NO₂S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

Original language	English
Pages (from-to)	o1413
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	69
Issue number	9
DOIs	https://doi.org/10.1107/S160053681302196X
State	Published - Sep 2013

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abstract = "In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.",

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T1 - Tert-butyl N-(thiophen-2-yl)carbamate

AU - Hsu, Gene C.

AU - Singer, Laci M.

AU - Cordes, David B.

AU - Findlater, Michael

PY - 2013/9

Y1 - 2013/9

N2 - In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

AB - In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C - H⋯O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N - H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

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U2 - 10.1107/S160053681302196X

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

Tert-butyl N-(thiophen-2-yl)carbamate

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