Temperature-dependence of the low-frequency spectrum of 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide studied by optical Kerr effect spectroscopy

Justin Rajesh Rajian; Shengfu Li; Richard A. Bartsch; Edward L. Quitevis

doi:10.1016/j.cplett.2004.06.068

Temperature-dependence of the low-frequency spectrum of 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide studied by optical Kerr effect spectroscopy

Justin Rajesh Rajian, Shengfu Li, Richard A. Bartsch, Edward L. Quitevis

Chemistry and Biochemistry

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Abstract

The spectrum of the ionic liquid, 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, in the 0-250 cm^-1 region was studied as a function of temperature from 280 to 393 K. The spectra were obtained by using optical Kerr effect spectroscopy. The intermolecular part of the spectrum can be decomposed into two components. The first spectral moments of both components decrease with temperature. However, the width of the low-frequency component decreases with temperature, while that of the high-frequency component increases and then remains constant above 323 K. This difference is interpreted as being due to the mixed intermolecular/ intramolecular character of the high-frequency component.

Original language	English
Pages (from-to)	372-377
Number of pages	6
Journal	Chemical Physics Letters
Volume	393
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2004.06.068
State	Published - Aug 1 2004

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@article{3c001bfc678f433caac34b71525eebff,

title = "Temperature-dependence of the low-frequency spectrum of 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide studied by optical Kerr effect spectroscopy",

abstract = "The spectrum of the ionic liquid, 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, in the 0-250 cm-1 region was studied as a function of temperature from 280 to 393 K. The spectra were obtained by using optical Kerr effect spectroscopy. The intermolecular part of the spectrum can be decomposed into two components. The first spectral moments of both components decrease with temperature. However, the width of the low-frequency component decreases with temperature, while that of the high-frequency component increases and then remains constant above 323 K. This difference is interpreted as being due to the mixed intermolecular/ intramolecular character of the high-frequency component.",

author = "{Rajesh Rajian}, Justin and Shengfu Li and Bartsch, {Richard A.} and Quitevis, {Edward L.}",

note = "Funding Information: We gratefully acknowledge the support of this research by the Welch Foundation.",

year = "2004",

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doi = "10.1016/j.cplett.2004.06.068",

language = "English",

volume = "393",

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Temperature-dependence of the low-frequency spectrum of 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide studied by optical Kerr effect spectroscopy. / Rajesh Rajian, Justin; Li, Shengfu; Bartsch, Richard A.; Quitevis, Edward L.

In: Chemical Physics Letters, Vol. 393, No. 4-6, 01.08.2004, p. 372-377.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Temperature-dependence of the low-frequency spectrum of 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide studied by optical Kerr effect spectroscopy

AU - Rajesh Rajian, Justin

AU - Li, Shengfu

AU - Bartsch, Richard A.

AU - Quitevis, Edward L.

N1 - Funding Information: We gratefully acknowledge the support of this research by the Welch Foundation.

PY - 2004/8/1

Y1 - 2004/8/1

N2 - The spectrum of the ionic liquid, 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, in the 0-250 cm-1 region was studied as a function of temperature from 280 to 393 K. The spectra were obtained by using optical Kerr effect spectroscopy. The intermolecular part of the spectrum can be decomposed into two components. The first spectral moments of both components decrease with temperature. However, the width of the low-frequency component decreases with temperature, while that of the high-frequency component increases and then remains constant above 323 K. This difference is interpreted as being due to the mixed intermolecular/ intramolecular character of the high-frequency component.

AB - The spectrum of the ionic liquid, 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, in the 0-250 cm-1 region was studied as a function of temperature from 280 to 393 K. The spectra were obtained by using optical Kerr effect spectroscopy. The intermolecular part of the spectrum can be decomposed into two components. The first spectral moments of both components decrease with temperature. However, the width of the low-frequency component decreases with temperature, while that of the high-frequency component increases and then remains constant above 323 K. This difference is interpreted as being due to the mixed intermolecular/ intramolecular character of the high-frequency component.

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U2 - 10.1016/j.cplett.2004.06.068

DO - 10.1016/j.cplett.2004.06.068

M3 - Article

AN - SCOPUS:3242889161

VL - 393

SP - 372

EP - 377

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -

Temperature-dependence of the low-frequency spectrum of 1-pentyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide studied by optical Kerr effect spectroscopy

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