Synthesis, Structure and Reactivity of Novel Oligosilyl Anions

Helmut Reinke, C. Krempner

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

1 Scopus citations

Abstract

The synthesis of the sterically overcrowded oligosilyl anions tris[methylbis(trimethylsilyl)sily1]silylpotassium [TBTS-K], -lithium [TBTS-Li] (2) and heptakis(trimethylsilyl)tetrasilacyclobutylpotassium [HTSB-K] (9) is reported. The new oligosilanes, TBTS-SiF3 (9,TB TS-SiF2Ph (6) and TBTS-SiH20Ph (7) were readily prepared by treatment of 2 with SiF4, PhSiF3 and (PhO)3SiH, respectively. The molecular structure of 6 has been derived from X-ray diffraction data. The reaction of 9 with SiF4, PhSiF3 and PhSiH2Cl led to the formation of the cyclic oligosilanes HTSB-SiF3 (lo), HTSB-SiF2Ph (11) and HTSB-SiH2Ph (12), respectively.

Original languageEnglish
Title of host publicationOrganosilicon Chemistry Set
Subtitle of host publicationFrom Molecules to Materials
PublisherWiley
Pages217-221
Number of pages5
ISBN (Electronic)9783527620777
ISBN (Print)9783527323470
DOIs
StatePublished - Jun 10 2008

Keywords

  • Chlorosilanes
  • Fluorosilanes
  • Oligosilanes
  • Oligosilyl anions

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