@article{4210d53227c7446485b010283f3de083,
title = "Synthesis of Tribenzo[b,e,g]phosphindole Oxides via Radical Bicyclization Cascades of o-Arylalkynylanilines",
abstract = "A new DTBP/Mg(NO3)2-mediated bicyclization cascade of o-arylalkynylanilines with secondary arylphosphine oxides has been developed, enabling dual C(sp2)-H functionalization along with the cleavage of the C-N bond. The combination between regioselective P-centered radical-triggered [3 + 2] cyclization and C-centered radical-induced cross-coupling in a one-pot manner delivered 27 examples of tribenzo[b,e,g]phosphindole oxides with generally high regioselectivity. A reasonable mechanism for forming such products involving radical addition-cyclization cascade is proposed.",
author = "Jie Li and Zhang, {Wen Wen} and Wei, {Xiao Jing} and Hao, {Wen Juan} and Guigen Li and Tu, {Shu Jiang} and Bo Jiang",
note = "Funding Information: We are grateful for financial support from the NSFC (Nos. 21232004, 21472071, and 21602087), PAPD of Jiangsu Higher Education Institutions, the Outstanding Youth Fund of JSNU (YQ2015003), NSF of Jiangsu Province (BK20151163 and BK20160212), the Qing Lan Project, and NSF of Jiangsu Education Committee (15KJB150006). Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2017",
month = sep,
day = "1",
doi = "10.1021/acs.orglett.7b02071",
language = "English",
volume = "19",
pages = "4512--4515",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society (ACS)",
number = "17",
}