TY - JOUR
T1 - Synthesis of Novel Steroidal Boranes
AU - Roy, Debloleena
AU - Birney, David M.
N1 - Funding Information:
Acknowledgment is made to the Donors of The Petroleum Research Fund, administered by the American Chemical Society, for the support of this research. We are grateful for many helpful discussions with Dr. Robert D.Walkup.
Publisher Copyright:
© 1994 Georg Thieme Verlag. All rights reserved.
PY - 1994/10
Y1 - 1994/10
N2 - The dimethoxyketone 3, synthesized selectively and in high yield from methyl deoxycholate (1), served as a common precursor to three novel steroidal boranes (5, 7, and 10). The complexation behavior of these boranes was probed both by NMR studies and by using them as Diels-Alder catalysts. In the latter case, modest enantiomeric excesses were obtained.
AB - The dimethoxyketone 3, synthesized selectively and in high yield from methyl deoxycholate (1), served as a common precursor to three novel steroidal boranes (5, 7, and 10). The complexation behavior of these boranes was probed both by NMR studies and by using them as Diels-Alder catalysts. In the latter case, modest enantiomeric excesses were obtained.
UR - http://www.scopus.com/inward/record.url?scp=0001878166&partnerID=8YFLogxK
U2 - 10.1055/s-1994-23009
DO - 10.1055/s-1994-23009
M3 - Article
AN - SCOPUS:0001878166
SN - 0936-5214
VL - 1994
SP - 798
EP - 800
JO - Synlett
JF - Synlett
IS - 10
ER -