Synthesis of metalated pseudorotaxane polymers with full control over the average linear density of threaded macrocycles

Songsu Kang; M. Mustafa Cetin; Ruiyang Jiang; Eric S. Clevenger; Michael F. Mayer

doi:10.1021/ja507167k

Synthesis of metalated pseudorotaxane polymers with full control over the average linear density of threaded macrocycles

Songsu Kang, M. Mustafa Cetin, Ruiyang Jiang, Eric S. Clevenger, Michael F. Mayer

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Here we report the synthesis of metalated main-chain polypseudorotaxanes via ring-opening olefin metathesis copolymerization of macrocycles and metalated [2]catenanes. By varying the feed ratio of the macrocycle and the [2]catenate comonomers, we prepared metalated pseudorotaxane polymers with selected, predictable average linear densities of threaded macrocycles that ranged from 0% to 100%, thus allowing, for the first time, both full and fine control over this key parameter.

Original language	English
Pages (from-to)	12588-12591
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	36
DOIs	https://doi.org/10.1021/ja507167k
State	Published - Sep 10 2014

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title = "Synthesis of metalated pseudorotaxane polymers with full control over the average linear density of threaded macrocycles",

abstract = "Here we report the synthesis of metalated main-chain polypseudorotaxanes via ring-opening olefin metathesis copolymerization of macrocycles and metalated [2]catenanes. By varying the feed ratio of the macrocycle and the [2]catenate comonomers, we prepared metalated pseudorotaxane polymers with selected, predictable average linear densities of threaded macrocycles that ranged from 0% to 100%, thus allowing, for the first time, both full and fine control over this key parameter.",

author = "Songsu Kang and Cetin, {M. Mustafa} and Ruiyang Jiang and Clevenger, {Eric S.} and Mayer, {Michael F.}",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

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AU - Kang, Songsu

AU - Cetin, M. Mustafa

AU - Jiang, Ruiyang

AU - Clevenger, Eric S.

AU - Mayer, Michael F.

PY - 2014/9/10

Y1 - 2014/9/10

N2 - Here we report the synthesis of metalated main-chain polypseudorotaxanes via ring-opening olefin metathesis copolymerization of macrocycles and metalated [2]catenanes. By varying the feed ratio of the macrocycle and the [2]catenate comonomers, we prepared metalated pseudorotaxane polymers with selected, predictable average linear densities of threaded macrocycles that ranged from 0% to 100%, thus allowing, for the first time, both full and fine control over this key parameter.

AB - Here we report the synthesis of metalated main-chain polypseudorotaxanes via ring-opening olefin metathesis copolymerization of macrocycles and metalated [2]catenanes. By varying the feed ratio of the macrocycle and the [2]catenate comonomers, we prepared metalated pseudorotaxane polymers with selected, predictable average linear densities of threaded macrocycles that ranged from 0% to 100%, thus allowing, for the first time, both full and fine control over this key parameter.

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IS - 36

ER -

Synthesis of metalated pseudorotaxane polymers with full control over the average linear density of threaded macrocycles

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