Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

Alan H. Cowley; Jon G. Lasch; Nicholas C. Norman; Marek Pakulski; Bruce R. Whittlesey

doi:10.1039/C39830000881

Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

Alan H. Cowley, Jon G. Lasch, Nicholas C. Norman, Marek Pakulski, Bruce R. Whittlesey

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

The reaction of (Me₃Si)₂CHMCl₂ (M = As or Sb) with (2,4,6-Bu^t₃C₆H₂)PH ₂ in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-Bu^t₃C₆H ₂)P=MCH(SiMe₃)₂ (M = As or Sb).

Original language	English
Pages (from-to)	881-882
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39830000881
State	Published - 1983

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@article{459bcf064d204cb29a07493ac1c4000e,

title = "Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds",

abstract = "The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).",

author = "Cowley, {Alan H.} and Lasch, {Jon G.} and Norman, {Nicholas C.} and Marek Pakulski and Whittlesey, {Bruce R.}",

year = "1983",

doi = "10.1039/C39830000881",

language = "English",

pages = "881--882",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "16",

}

Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds. / Cowley, Alan H.; Lasch, Jon G.; Norman, Nicholas C.; Pakulski, Marek; Whittlesey, Bruce R.

In: Journal of the Chemical Society, Chemical Communications, No. 16, 1983, p. 881-882.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

AU - Cowley, Alan H.

AU - Lasch, Jon G.

AU - Norman, Nicholas C.

AU - Pakulski, Marek

AU - Whittlesey, Bruce R.

PY - 1983

Y1 - 1983

N2 - The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).

AB - The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).

UR - http://www.scopus.com/inward/record.url?scp=37049093529&partnerID=8YFLogxK

U2 - 10.1039/C39830000881

DO - 10.1039/C39830000881

M3 - Article

AN - SCOPUS:37049093529

SP - 881

EP - 882

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

IS - 16

ER -

Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

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