Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

Alan H. Cowley, Jon G. Lasch, Nicholas C. Norman, Marek Pakulski, Bruce R. Whittlesey

Research output: Contribution to journalArticle

70 Scopus citations

Abstract

The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).

Original languageEnglish
Pages (from-to)881-882
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number16
DOIs
StatePublished - 1983

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