TY - JOUR
T1 - Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds
AU - Cowley, Alan H.
AU - Lasch, Jon G.
AU - Norman, Nicholas C.
AU - Pakulski, Marek
AU - Whittlesey, Bruce R.
PY - 1983
Y1 - 1983
N2 - The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).
AB - The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).
UR - http://www.scopus.com/inward/record.url?scp=37049093529&partnerID=8YFLogxK
U2 - 10.1039/C39830000881
DO - 10.1039/C39830000881
M3 - Article
AN - SCOPUS:37049093529
SP - 881
EP - 882
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 16
ER -