Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

Alan H. Cowley; Jon G. Lasch; Nicholas C. Norman; Marek Pakulski; Bruce R. Whittlesey

doi:10.1039/C39830000881

Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds

Alan H. Cowley, Jon G. Lasch, Nicholas C. Norman, Marek Pakulski, Bruce R. Whittlesey

Chemistry and Biochemistry

Research output: Contribution to journal › Article

70 Scopus citations

Abstract

The reaction of (Me₃Si)₂CHMCl₂ (M = As or Sb) with (2,4,6-Bu^t₃C₆H₂)PH ₂ in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-Bu^t₃C₆H ₂)P=MCH(SiMe₃)₂ (M = As or Sb).

Original language	English
Pages (from-to)	881-882
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39830000881
State	Published - 1983

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Cowley, A. H., Lasch, J. G., Norman, N. C., Pakulski, M., & Whittlesey, B. R. (1983). Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus-arsenic and phosphorus-antimony double bonds. Journal of the Chemical Society, Chemical Communications, (16), 881-882. https://doi.org/10.1039/C39830000881

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abstract = "The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).",

author = "Cowley, {Alan H.} and Lasch, {Jon G.} and Norman, {Nicholas C.} and Marek Pakulski and Whittlesey, {Bruce R.}",

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pages = "881--882",

journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Cowley, Alan H.

AU - Lasch, Jon G.

AU - Norman, Nicholas C.

AU - Pakulski, Marek

AU - Whittlesey, Bruce R.

PY - 1983

Y1 - 1983

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AB - The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-But3C6H2)PH 2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H 2)P=MCH(SiMe3)2 (M = As or Sb).

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