Synthesis of 2-Aryl Derivatives of Pentaborane(9)

Joseph A. Heppert; Donald F. Gaines

doi:10.1021/ic00142a002

Synthesis of 2-Aryl Derivatives of Pentaborane(9)

Joseph A. Heppert, Donald F. Gaines

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Abstract

A series of 2-aryl derivatives of B₅H₉ have been prepared via aluminum chloride catalyzed electrophilic substitution by 2-ClB₅H₈ on various alkylbenzenes. Analyses of ¹H NMR spectra suggest that the site of attack of the B₅H₈ moiety is controlled by steric interactions.

Original language	English
Pages (from-to)	4117-4121
Number of pages	5
Journal	Inorganic Chemistry
Volume	21
Issue number	12
DOIs	https://doi.org/10.1021/ic00142a002
State	Published - 1982

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title = "Synthesis of 2-Aryl Derivatives of Pentaborane(9)",

abstract = "A series of 2-aryl derivatives of B5H9 have been prepared via aluminum chloride catalyzed electrophilic substitution by 2-ClB5H8 on various alkylbenzenes. Analyses of 1H NMR spectra suggest that the site of attack of the B5H8 moiety is controlled by steric interactions.",

author = "Heppert, {Joseph A.} and Gaines, {Donald F.}",

year = "1982",

doi = "10.1021/ic00142a002",

language = "English",

volume = "21",

pages = "4117--4121",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "12",

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T1 - Synthesis of 2-Aryl Derivatives of Pentaborane(9)

AU - Heppert, Joseph A.

AU - Gaines, Donald F.

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N2 - A series of 2-aryl derivatives of B5H9 have been prepared via aluminum chloride catalyzed electrophilic substitution by 2-ClB5H8 on various alkylbenzenes. Analyses of 1H NMR spectra suggest that the site of attack of the B5H8 moiety is controlled by steric interactions.

AB - A series of 2-aryl derivatives of B5H9 have been prepared via aluminum chloride catalyzed electrophilic substitution by 2-ClB5H8 on various alkylbenzenes. Analyses of 1H NMR spectra suggest that the site of attack of the B5H8 moiety is controlled by steric interactions.

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U2 - 10.1021/ic00142a002

DO - 10.1021/ic00142a002

M3 - Article

AN - SCOPUS:4243775715

SN - 0020-1669

VL - 21

SP - 4117

EP - 4121

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Synthesis of 2-Aryl Derivatives of Pentaborane(9)

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