TY - JOUR
T1 - Synthesis and structure of boron-bithiazole complexes
AU - Findlater, Michael
AU - Swisher, Nicholas S.
AU - White, Peter S.
PY - 2010/12
Y1 - 2010/12
N2 - The syntheses of the first reported p-block complexes of the bithiazole moiety are reported, namely [(tBuBTz)BBr2][Br] (3), and [(PhBTz)BBr2][Br] (4) (tBuBTz = 4,4′-di-tert-butyl-2,2′- bithiazole and PhBTz = 4,4′-diphenyl-2,2′-bithiazole). Compounds 3 and 4 were prepared via reaction of equimolar quantities of the appropriate bithiazole ligand with BBr3. The molecular structures of 3, and the known compound PhBTz (2) were established using single-crystal X-ray diffraction techniques.
AB - The syntheses of the first reported p-block complexes of the bithiazole moiety are reported, namely [(tBuBTz)BBr2][Br] (3), and [(PhBTz)BBr2][Br] (4) (tBuBTz = 4,4′-di-tert-butyl-2,2′- bithiazole and PhBTz = 4,4′-diphenyl-2,2′-bithiazole). Compounds 3 and 4 were prepared via reaction of equimolar quantities of the appropriate bithiazole ligand with BBr3. The molecular structures of 3, and the known compound PhBTz (2) were established using single-crystal X-ray diffraction techniques.
KW - Bithiazole ligands
KW - Boron
KW - Boronium cations
UR - http://www.scopus.com/inward/record.url?scp=78649611563&partnerID=8YFLogxK
U2 - 10.1002/ejic.201000940
DO - 10.1002/ejic.201000940
M3 - Article
AN - SCOPUS:78649611563
SN - 1434-1948
SP - 5379
EP - 5382
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 34
ER -