Synthesis and Complex Chemistry of Novel Di- and Trihydroxyoligosilanes

D. Hoffmann, H. Reinke, C. Krempner

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

The synthesis of the novel bidentate ligands (HORMeSi)2 [R = Si(SiMe3)3] (2) and (HOR2Si)2SiMe2 [R = SiMe3] (7) as well as the tridentate ligands (HORMeSi)3SiMe (10a) [R = Si(SiMe3)3] and (10b) [R = SiMe(SiMe3)2] is reported. New cyclic metal siloxide complexes were readily prepared from the reaction of 2 and 7 with Ti(OEt)4, Ti(NEt2)4 and Zr(NEt2)4, respectively. The solid-state structures of the novel complexes TiL2 (3) and LTi(OEt)2 (4) [L = (2) - 2H] were determined by X-ray crystallography. Treatment of 10b with CpTiCl3 resulted in the formation of the novel tridentate complex CpTi-(OSiMeR)3SiMe (11).

Original languageEnglish
Title of host publicationOrganosilicon Chemistry Set
Subtitle of host publicationFrom Molecules to Materials
PublisherWiley
Pages420-424
Number of pages5
ISBN (Electronic)9783527620777
ISBN (Print)9783527323470
DOIs
StatePublished - Jun 10 2008

Keywords

  • Metal siloxides
  • Oligosilanes
  • Silanols
  • Titanium
  • Zirconium

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    Hoffmann, D., Reinke, H., & Krempner, C. (2008). Synthesis and Complex Chemistry of Novel Di- and Trihydroxyoligosilanes. In Organosilicon Chemistry Set: From Molecules to Materials (pp. 420-424). Wiley. https://doi.org/10.1002/9783527620777.ch68d