Synthesis and characterization of a β-diketiminate-supported aluminum dication

Dragoslav Vidovic; Michael Findlater; Gregor Reeske; Alan H. Cowley

doi:10.1016/j.jorganchem.2007.10.003

Synthesis and characterization of a β-diketiminate-supported aluminum dication

Dragoslav Vidovic, Michael Findlater, Gregor Reeske, Alan H. Cowley

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A base-stabilized mononuclear aluminum dication has been prepared by extrusion of two triflate anions from a precursor β-diketiminate-supported aluminum bis(triflate) using the tris(2-aminoethyl)amine (tren) ligand.

Original language	English
Pages (from-to)	5683-5686
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	692
Issue number	26
DOIs	https://doi.org/10.1016/j.jorganchem.2007.10.003
State	Published - Dec 15 2007

Keywords

Aluminum
Dication
Triflate
X-ray structure
β-Diketiminate

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10.1016/j.jorganchem.2007.10.003

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title = "Synthesis and characterization of a β-diketiminate-supported aluminum dication",

abstract = "A base-stabilized mononuclear aluminum dication has been prepared by extrusion of two triflate anions from a precursor β-diketiminate-supported aluminum bis(triflate) using the tris(2-aminoethyl)amine (tren) ligand.",

keywords = "Aluminum, Dication, Triflate, X-ray structure, β-Diketiminate",

author = "Dragoslav Vidovic and Michael Findlater and Gregor Reeske and Cowley, {Alan H.}",

note = "Funding Information: We are grateful to the Robert A. Welch Foundation (F-0003) for financial support of this work.",

year = "2007",

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day = "15",

doi = "10.1016/j.jorganchem.2007.10.003",

language = "English",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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T1 - Synthesis and characterization of a β-diketiminate-supported aluminum dication

AU - Vidovic, Dragoslav

AU - Findlater, Michael

AU - Reeske, Gregor

AU - Cowley, Alan H.

N1 - Funding Information: We are grateful to the Robert A. Welch Foundation (F-0003) for financial support of this work.

PY - 2007/12/15

Y1 - 2007/12/15

N2 - A base-stabilized mononuclear aluminum dication has been prepared by extrusion of two triflate anions from a precursor β-diketiminate-supported aluminum bis(triflate) using the tris(2-aminoethyl)amine (tren) ligand.

AB - A base-stabilized mononuclear aluminum dication has been prepared by extrusion of two triflate anions from a precursor β-diketiminate-supported aluminum bis(triflate) using the tris(2-aminoethyl)amine (tren) ligand.

KW - Aluminum

KW - Dication

KW - Triflate

KW - X-ray structure

KW - β-Diketiminate

UR - http://www.scopus.com/inward/record.url?scp=36248934243&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2007.10.003

DO - 10.1016/j.jorganchem.2007.10.003

M3 - Article

AN - SCOPUS:36248934243

SN - 0022-328X

VL - 692

SP - 5683

EP - 5686

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 26

ER -

Synthesis and characterization of a β-diketiminate-supported aluminum dication

Abstract

Keywords

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