TY - JOUR
T1 - Sustainable recycling of benzoic acid production waste
T2 - Green and highly efficient methods to separate and recover high value-added conjugated aromatic compounds from industrial residues
AU - Zhang, Xin
AU - Qiao, Pengwei
AU - Ji, Xuan
AU - Han, Junbin
AU - Liu, Lili
AU - Weeks, Brandon L.
AU - Yao, Qingwei
AU - Zhang, Zhao
PY - 2013/8/5
Y1 - 2013/8/5
N2 - Industrial residues formed in the industrial production of benzoic acid by cobalt-catalyzed oxidation of toluene are traditionally disposed as waste materials and often burnt or buried. It therefore may become a significant source of environmental pollution. In this report, we describe simple techniques to obtain high value conjugated aromatic compounds, including 9-fluorenone, 6H-benzo[c]chromen-6-one, biphenyl-3-carboxylic acid, and biphenyl-4-carboxylic acid, from benzoic acid industrial residue using inexpensive alkalis and acids. The separation methods involve simple and mild procedures with high economic effectiveness and low environmental contamination.
AB - Industrial residues formed in the industrial production of benzoic acid by cobalt-catalyzed oxidation of toluene are traditionally disposed as waste materials and often burnt or buried. It therefore may become a significant source of environmental pollution. In this report, we describe simple techniques to obtain high value conjugated aromatic compounds, including 9-fluorenone, 6H-benzo[c]chromen-6-one, biphenyl-3-carboxylic acid, and biphenyl-4-carboxylic acid, from benzoic acid industrial residue using inexpensive alkalis and acids. The separation methods involve simple and mild procedures with high economic effectiveness and low environmental contamination.
KW - 6H-Benzo[c]chromen-6-one
KW - 9-Fluorenone
KW - Benzoic acid industrial residue
KW - Biphenyl carboxylic acids
KW - Sustainable chemistry
UR - http://www.scopus.com/inward/record.url?scp=84881402799&partnerID=8YFLogxK
U2 - 10.1021/sc400059j
DO - 10.1021/sc400059j
M3 - Article
AN - SCOPUS:84881402799
SN - 2168-0485
VL - 1
SP - 974
EP - 981
JO - ACS Sustainable Chemistry and Engineering
JF - ACS Sustainable Chemistry and Engineering
IS - 8
ER -