Surface Infrared Spectroelectrochemistry. The Interaction of the Electric Field in the Electrical Double Layer with Pyrene Adsorbed on a Platinum Electrode: Effects on the Infrared Surface Difference Spectrum

Carol Korzeniewski, Stanley Pons

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The surface infrared spectrum of pyrene adsorbed at a platinum electrode is obtained by using the SNIFTIRS technique. Activation of Raman modes by coupling of the polarizable electrons in the molecule to the strong electric field field which exists across the electrical double layer is reported. SNIFTIRS spectra are compared to both the solution IR and Raman spectra.

Original languageEnglish
Pages (from-to)468-471
Number of pages4
JournalLangmuir
Volume2
Issue number4
DOIs
StatePublished - 1986

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