TY - JOUR
T1 - Streaming potential studies of colloid, polyelectrolyte and protein deposition
AU - Adamczyk, Z.
AU - Sadlej, K.
AU - Wajnryb, E.
AU - Nattich, M.
AU - Ekiel-Jezewska, M. L.
AU - Bławzdziewicz, J.
N1 - Funding Information:
This work was supported by the Polish Ministry of Science and Higher Education (MNiSzW) grants N205 022311112 , N507 04831208 , the COST Action D43 Grant and by the NSF CAREER Grant No. CBET-0348175 .
PY - 2010/1/15
Y1 - 2010/1/15
N2 - Recent developments in the electrokinetic determination of particle, protein and polyelectrolyte monolayers at solid/electrolyte interfaces, are reviewed. Illustrative theoretical results characterizing particle transport to interfaces are presented, especially analytical formulae for the limiting flux under various deposition regimes and expressions for diffusion coefficients of various particle shapes. Then, blocking effects appearing for higher surface coverage of particles are characterized in terms of the random sequential adsorption model. These theoretical predictions are used for interpretation of experimental results obtained for colloid particles and proteins under convection and diffusion transport conditions. The kinetics of particle deposition and the structure of monolayers are analyzed quantitatively in terms of the generalized random sequential adsorption (RSA) model, considering the coupling of the bulk and surface transport steps. Experimental results are also discussed, showing the dependence of the jamming coverage of monolayers on the ionic strength of particle suspensions. In the next section, theoretical and experimental results pertaining to electrokinetics of particle covered surfaces are presented. Theoretical models are discussed, enabling a quantitative evaluation of the streaming current and the streaming potential as a function of particle coverage and their surface properties (zeta potential). Experimental data related to electrokinetic characteristics of particle monolayers, mostly streaming potential measurements, are presented and interpreted in terms of the above theoretical approaches. These results, obtained for model systems of monodisperse colloid particles are used as reference data for discussion of experiments performed for polyelectrolyte and protein covered surfaces. The utility of the electrokinetic measurements for a precise, in situ determination of particle and protein monolayers at various interfaces is pointed out.
AB - Recent developments in the electrokinetic determination of particle, protein and polyelectrolyte monolayers at solid/electrolyte interfaces, are reviewed. Illustrative theoretical results characterizing particle transport to interfaces are presented, especially analytical formulae for the limiting flux under various deposition regimes and expressions for diffusion coefficients of various particle shapes. Then, blocking effects appearing for higher surface coverage of particles are characterized in terms of the random sequential adsorption model. These theoretical predictions are used for interpretation of experimental results obtained for colloid particles and proteins under convection and diffusion transport conditions. The kinetics of particle deposition and the structure of monolayers are analyzed quantitatively in terms of the generalized random sequential adsorption (RSA) model, considering the coupling of the bulk and surface transport steps. Experimental results are also discussed, showing the dependence of the jamming coverage of monolayers on the ionic strength of particle suspensions. In the next section, theoretical and experimental results pertaining to electrokinetics of particle covered surfaces are presented. Theoretical models are discussed, enabling a quantitative evaluation of the streaming current and the streaming potential as a function of particle coverage and their surface properties (zeta potential). Experimental data related to electrokinetic characteristics of particle monolayers, mostly streaming potential measurements, are presented and interpreted in terms of the above theoretical approaches. These results, obtained for model systems of monodisperse colloid particles are used as reference data for discussion of experiments performed for polyelectrolyte and protein covered surfaces. The utility of the electrokinetic measurements for a precise, in situ determination of particle and protein monolayers at various interfaces is pointed out.
KW - Colloid deposition
KW - Nanoparticle deposition
KW - Particle covered surfaces
KW - Polyelectrolyte deposition
KW - Protein deposition
KW - Streaming potential of covered surfaces
UR - http://www.scopus.com/inward/record.url?scp=75449084722&partnerID=8YFLogxK
U2 - 10.1016/j.cis.2009.09.004
DO - 10.1016/j.cis.2009.09.004
M3 - Review article
C2 - 19926067
AN - SCOPUS:75449084722
SN - 0001-8686
VL - 153
SP - 1
EP - 29
JO - Advances in Colloid and Interface Science
JF - Advances in Colloid and Interface Science
IS - 1-2
ER -