Stable Carbon and Nitrogen Isotope Ratios of Sodium and Potassium Cyanide as a Forensic Signature

Helen W. Kreuzer, Juske Horita, James J. Moran, Bruce A. Tomkins, Derek B. Janszen, April Carman

Research output: Contribution to journalArticle

12 Scopus citations

Abstract

Sodium and potassium cyanide are highly toxic, produced in large amounts by the chemical industry, and linked to numerous high-profile crimes. The U.S. Centers for Disease Control and Prevention has identified cyanide as one of the most probable agents to be used in a chemical terrorism event. We investigated whether stable C and N isotopic content of sodium and potassium cyanide could serve as a forensic signature for sample matching, using a collection of 65 cyanide samples. Upon analysis, a few of the cyanide samples displayed nonhomogeneous isotopic content associated with degradation to a carbonate salt and loss of hydrogen cyanide. Most samples had highly reproducible isotope content. Of the 65 cyanide samples, >95% could be properly matched based on C and N isotope ratios, with a false match rate <3%. These results suggest that stable C and N isotope ratios are a useful forensic signature for matching cyanide samples.

Original languageEnglish
Pages (from-to)75-79
Number of pages5
JournalJournal of Forensic Sciences
Volume57
Issue number1
DOIs
StatePublished - Jan 2012

Keywords

  • Forensic science
  • Isotope ratio mass spectrometry
  • Potassium cyanide
  • Sample matching
  • Sodium cyanide

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