Abstract
A model Hamiltonian, which a previous study has shown contains many quasi-periodic trajectories, is investigated semiclassically. Eigenvalues are evaluated by using the method of surfaces of section. Quantizable levels which include many resonances exist both below and above the unimolecular threshold. A pattern, dependent upon the number of quanta in the reaction coordinate, is found for the quasi-periodic trajectories.
Original language | English |
---|---|
Pages (from-to) | 2873-2879 |
Number of pages | 7 |
Journal | Journal of physical chemistry |
Volume | 86 |
Issue number | 15 |
DOIs | |
State | Published - 1982 |