Rhodium-catalyzed direct synthesis of unprotected NH-sulfoximines from sulfoxides

Jinmin Miao, Nigel G.J. Richards, Haibo Ge

Research output: Contribution to journalArticle

38 Scopus citations

Abstract

A novel rhodium-catalyzed imination of sulfoxides using O-(2,4-dinitrophenyl)hydroxylamine is developed under mild conditions with good functional group tolerance. This method provides an efficient access to free NH-sulfoximines, an important structural unit in a variety of biologically active compounds.

Original languageEnglish
Pages (from-to)9687-9689
Number of pages3
JournalChemical Communications
Volume50
Issue number68
DOIs
StatePublished - Jul 29 2014

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