Recent Advances in the Application of Selectfluor as a “Fluorine-free” Functional Reagent in Organic Synthesis

Ke Yang; Mengjie Song; Ahmed I.M. Ali; Syed M. Mudassir; Haibo Ge

doi:10.1002/asia.202000011

Recent Advances in the Application of Selectfluor as a “Fluorine-free” Functional Reagent in Organic Synthesis

Ke Yang, Mengjie Song, Ahmed I.M. Ali, Syed M. Mudassir, Haibo Ge

Chemistry and Biochemistry

Research output: Contribution to journal › Review article › peer-review

7 Scopus citations

Abstract

Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine-free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine-free” functionalizations over the last five years.

Original language	English
Pages (from-to)	729-741
Number of pages	13
Journal	Chemistry - An Asian Journal
Volume	15
Issue number	6
DOIs	https://doi.org/10.1002/asia.202000011
State	Published - Mar 16 2020

Keywords

Selectfluor
electrophilic fluorinating reagent
organic synthesis
“fluorine-free” functional reagent

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title = "Recent Advances in the Application of Selectfluor as a “Fluorine-free” Functional Reagent in Organic Synthesis",

abstract = "Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine-free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine-free” functionalizations over the last five years.",

keywords = "Selectfluor, electrophilic fluorinating reagent, organic synthesis, “fluorine-free” functional reagent",

author = "Ke Yang and Mengjie Song and Ali, {Ahmed I.M.} and Mudassir, {Syed M.} and Haibo Ge",

year = "2020",

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T1 - Recent Advances in the Application of Selectfluor as a “Fluorine-free” Functional Reagent in Organic Synthesis

AU - Yang, Ke

AU - Song, Mengjie

AU - Ali, Ahmed I.M.

AU - Mudassir, Syed M.

AU - Ge, Haibo

PY - 2020/3/16

Y1 - 2020/3/16

N2 - Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine-free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine-free” functionalizations over the last five years.

AB - Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine-free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine-free” functionalizations over the last five years.

KW - Selectfluor

KW - electrophilic fluorinating reagent

KW - organic synthesis

KW - “fluorine-free” functional reagent

UR - http://www.scopus.com/inward/record.url?scp=85081356704&partnerID=8YFLogxK

U2 - 10.1002/asia.202000011

DO - 10.1002/asia.202000011

M3 - Review article

C2 - 32068956

AN - SCOPUS:85081356704

VL - 15

SP - 729

EP - 741

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

SN - 1861-4728

IS - 6

ER -