TY - JOUR
T1 - Recent Advances in the Application of Selectfluor as a “Fluorine-free” Functional Reagent in Organic Synthesis
AU - Yang, Ke
AU - Song, Mengjie
AU - Ali, Ahmed I.M.
AU - Mudassir, Syed M.
AU - Ge, Haibo
N1 - Funding Information:
We gratefully acknowledge NSF (CHE-1350541 and 1855735), Indiana University Purdue University Indianapolis, and Texas Tech University for financial support. Ke Yang is grateful for financial support from NSFC: (No. 21702019) and Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University.
Publisher Copyright:
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2020/3/16
Y1 - 2020/3/16
N2 - Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine-free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine-free” functionalizations over the last five years.
AB - Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine-free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine-free” functionalizations over the last five years.
KW - Selectfluor
KW - electrophilic fluorinating reagent
KW - organic synthesis
KW - “fluorine-free” functional reagent
UR - http://www.scopus.com/inward/record.url?scp=85081356704&partnerID=8YFLogxK
U2 - 10.1002/asia.202000011
DO - 10.1002/asia.202000011
M3 - Review article
C2 - 32068956
AN - SCOPUS:85081356704
VL - 15
SP - 729
EP - 741
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
SN - 1861-4728
IS - 6
ER -