TY - JOUR
T1 - Recent Advances in First-Row-Transition-Metal-Catalyzed Dehydrogenative Coupling of C(sp3)-H Bonds
AU - Miao, Jinmin
AU - Ge, Haibo
N1 - Publisher Copyright:
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2015/12/1
Y1 - 2015/12/1
N2 - Transition-metal-catalyzed cross dehydrogenative coupling is a highly efficient tool for functionalization of C(sp3)-H bonds. In particular, the inexpensive first-row transition metals have been demonstrated as effective catalysts in this process. This microreview summarizes recent progress in two classes of first-row-transition-metal-catalyzed dehydrogenative reactions: intramolecular cyclization for C-C bond formation, and directed site-selective C-H functionalization. These transformations provide concise and practical approaches for preparation of various organic compounds, but so far they are underdeveloped.
AB - Transition-metal-catalyzed cross dehydrogenative coupling is a highly efficient tool for functionalization of C(sp3)-H bonds. In particular, the inexpensive first-row transition metals have been demonstrated as effective catalysts in this process. This microreview summarizes recent progress in two classes of first-row-transition-metal-catalyzed dehydrogenative reactions: intramolecular cyclization for C-C bond formation, and directed site-selective C-H functionalization. These transformations provide concise and practical approaches for preparation of various organic compounds, but so far they are underdeveloped.
KW - C-C coupling
KW - C-H activation
KW - Dehydrogenative coupling
KW - Homogeneous catalysis
KW - Nitrogen heterocycles
KW - Synthetic methods
UR - http://www.scopus.com/inward/record.url?scp=84948807194&partnerID=8YFLogxK
U2 - 10.1002/ejoc.201501186
DO - 10.1002/ejoc.201501186
M3 - Article
AN - SCOPUS:84948807194
SN - 1434-193X
VL - 2015
SP - 7859
EP - 7868
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 36
ER -