Abstract
The importance of reactive trajectories straying far from the minimum energy path is demonstrated for the bimolecular reaction H + HBr → H2(v-, j-) + Br at 53 kcal/mol collision energy. Product quantum state distributions are measured and calculated using the quasi-classical trajectory technique, and the calculations indicate that highly internally excited H2 products result from indirect reactive trajectories with bent transition states. A general argument is made suggesting that reaction products with internal energy exceeding a kinematic constraint can, in general, be attributed to reactive collisions straying far from the minimum energy path.
Original language | English |
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Pages (from-to) | 16368-16369 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 127 |
Issue number | 47 |
DOIs | |
State | Published - Nov 30 2005 |