Quantification of CO2 from electrochemical oxidation reactions with a strategy based on transmission infrared spectroscopy

Huiliang Huang; Carol Korzeniewski; Ganesh Vijayaraghavan

doi:10.1016/S0013-4686(02)00337-7

Quantification of CO₂ from electrochemical oxidation reactions with a strategy based on transmission infrared spectroscopy

Huiliang Huang, Carol Korzeniewski, Ganesh Vijayaraghavan

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The use of a micro-volume infrared transmission flow cell for quantitative determinations of CO₂ dissolved in solutions following electrochemical oxidation reactions is described. Results are compared with previous in situ infrared measurements as a step toward evaluating the performance of infrared spectroelectrochemical cells under conditions where non-ideal optical effects can become important. The electrochemical oxidation of formic acid on platinum is investigated as a model.

Original language	English
Pages (from-to)	3675-3679
Number of pages	5
Journal	Electrochimica Acta
Volume	47
Issue number	22-23
DOIs	https://doi.org/10.1016/S0013-4686(02)00337-7
State	Published - Aug 30 2002

Keywords

CO
Electrochemical oxidation
Transmission infrared spectroscopy

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10.1016/S0013-4686(02)00337-7

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title = "Quantification of CO2 from electrochemical oxidation reactions with a strategy based on transmission infrared spectroscopy",

abstract = "The use of a micro-volume infrared transmission flow cell for quantitative determinations of CO2 dissolved in solutions following electrochemical oxidation reactions is described. Results are compared with previous in situ infrared measurements as a step toward evaluating the performance of infrared spectroelectrochemical cells under conditions where non-ideal optical effects can become important. The electrochemical oxidation of formic acid on platinum is investigated as a model.",

keywords = "CO, Electrochemical oxidation, Transmission infrared spectroscopy",

author = "Huiliang Huang and Carol Korzeniewski and Ganesh Vijayaraghavan",

note = "Funding Information: We gratefully acknowledge the National Science Foundation (CHE-9727103) and Robert A. Welch Foundation for support of this work.",

year = "2002",

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doi = "10.1016/S0013-4686(02)00337-7",

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T1 - Quantification of CO2 from electrochemical oxidation reactions with a strategy based on transmission infrared spectroscopy

AU - Huang, Huiliang

AU - Korzeniewski, Carol

AU - Vijayaraghavan, Ganesh

N1 - Funding Information: We gratefully acknowledge the National Science Foundation (CHE-9727103) and Robert A. Welch Foundation for support of this work.

PY - 2002/8/30

Y1 - 2002/8/30

N2 - The use of a micro-volume infrared transmission flow cell for quantitative determinations of CO2 dissolved in solutions following electrochemical oxidation reactions is described. Results are compared with previous in situ infrared measurements as a step toward evaluating the performance of infrared spectroelectrochemical cells under conditions where non-ideal optical effects can become important. The electrochemical oxidation of formic acid on platinum is investigated as a model.

AB - The use of a micro-volume infrared transmission flow cell for quantitative determinations of CO2 dissolved in solutions following electrochemical oxidation reactions is described. Results are compared with previous in situ infrared measurements as a step toward evaluating the performance of infrared spectroelectrochemical cells under conditions where non-ideal optical effects can become important. The electrochemical oxidation of formic acid on platinum is investigated as a model.

KW - CO

KW - Electrochemical oxidation

KW - Transmission infrared spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=0037200206&partnerID=8YFLogxK

U2 - 10.1016/S0013-4686(02)00337-7

DO - 10.1016/S0013-4686(02)00337-7

M3 - Article

AN - SCOPUS:0037200206

SN - 0013-4686

VL - 47

SP - 3675

EP - 3679

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 22-23

ER -

Quantification of CO₂ from electrochemical oxidation reactions with a strategy based on transmission infrared spectroscopy

Abstract

Keywords

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