Positive thermal expansion facilitates the formation of argentophilic forces following an order-disorder phase transition

Navkiran Juneja, Daniel K. Unruh, Ryan H. Groeneman, Kristin M. Hutchins

Research output: Contribution to journalArticlepeer-review

Abstract

Argentophilic forces are formed in a coordination complex based on silver(i) trifluoromethanesulfonate and 4-stilbazole as a ligand. The forces are absent at low temperature and form as a result of an order-disorder phase transition that occurs upon heating. Colossal positive thermal expansion also precedes the phase transition.

Original languageEnglish
Pages (from-to)8898-8901
Number of pages4
JournalNew Journal of Chemistry
Volume45
Issue number20
DOIs
StatePublished - May 28 2021

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