Polypseudorotaxanes via ring-opening metathesis polymerizations of [2]catenanes

Songsu Kang, Brandon M. Berkshire, Zheng Xue, Manav Gupta, Christianah Layode, Preston A. May, Michael F. Mayer

Research output: Contribution to journalArticle

30 Scopus citations

Abstract

A bis-phenanthroline [2]catenane copper complex, consisting of one olefinic macrocycle and one nonolefinic macrocycle, underwent an entropy-driven ring-opening olefin metathesis polymerization (ROMP) to provide a polypseudorotaxane. The polymerization featured an average degree of polymerization of ca. 63 wherein the polymer was effectively saturated with threaded macrocycles. Removal of the copper led to near complete release of the macrocycles from the polymer backbone.

Original languageEnglish
Pages (from-to)15246-15247
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number46
DOIs
StatePublished - Nov 19 2008

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