TY - JOUR
T1 - Photovoltaic properties of graphene nanodisk-integrated polymer composites
AU - Ren, Liqiang
AU - Qiu, Jingjing
AU - Wang, Shiren
N1 - Funding Information:
The authors appreciate the funding support from 3M corporate, NSF career Grant, and Ed & Linda Whitacre Faculty Fellow Award.
PY - 2013
Y1 - 2013
N2 - Graphene nanodisks (GNDs) were synthesized through the intercalation of stacked graphene nanofibers and subsequent thermal exfoliation and reduction. The resultant GNDs were characterized by dynamic light scattering (DLS), transmission electron microscopy (TEM), atomic force microscope (AFM), and Thermogravimetric Analysis (TGA), along with Raman, optical absorption, and photoluminescence (PL) spectroscopies. The characterization results confirmed that as-produced GNDs were monolayer or few-layer thick with well-defined disk shape and uniform diameter of ∼40 nm, with a bandgap of 0.73 eV, HOMO -4.82 and LUMO -4.09. Subsequently, the as-produced GNDs were dispersed in poly(3-hexylthiophene), and the effect of GNDs dispersion morphology and loading fractions on photovoltaic properties were studied. High loading of GNDs resulted in many clusters and pinholes in the composites, and thus lowers the photovoltaic properties due to the shunt resistance. At low loading of GNDs, the composite morphology was very uniform, and the carrier mobility of the polymer composites was enhanced by 4-fold while the photocurrent was increased by 17%. As a result, the photovoltaic efficiency was increased around 8%. This work will significantly facilitate polymer nanocomposites for photovoltaic applications.
AB - Graphene nanodisks (GNDs) were synthesized through the intercalation of stacked graphene nanofibers and subsequent thermal exfoliation and reduction. The resultant GNDs were characterized by dynamic light scattering (DLS), transmission electron microscopy (TEM), atomic force microscope (AFM), and Thermogravimetric Analysis (TGA), along with Raman, optical absorption, and photoluminescence (PL) spectroscopies. The characterization results confirmed that as-produced GNDs were monolayer or few-layer thick with well-defined disk shape and uniform diameter of ∼40 nm, with a bandgap of 0.73 eV, HOMO -4.82 and LUMO -4.09. Subsequently, the as-produced GNDs were dispersed in poly(3-hexylthiophene), and the effect of GNDs dispersion morphology and loading fractions on photovoltaic properties were studied. High loading of GNDs resulted in many clusters and pinholes in the composites, and thus lowers the photovoltaic properties due to the shunt resistance. At low loading of GNDs, the composite morphology was very uniform, and the carrier mobility of the polymer composites was enhanced by 4-fold while the photocurrent was increased by 17%. As a result, the photovoltaic efficiency was increased around 8%. This work will significantly facilitate polymer nanocomposites for photovoltaic applications.
KW - A. Nano-structures
KW - A. Polymer-matrix composites (PMCs)
KW - A. Thin films
KW - B. Electrical properties
KW - B. Optical properties/techniques
UR - http://www.scopus.com/inward/record.url?scp=84881519616&partnerID=8YFLogxK
U2 - 10.1016/j.compositesb.2013.07.017
DO - 10.1016/j.compositesb.2013.07.017
M3 - Article
AN - SCOPUS:84881519616
SN - 1359-8368
VL - 55
SP - 548
EP - 557
JO - Composites Part B: Engineering
JF - Composites Part B: Engineering
ER -