Pentacarbonyl(trimethylamine)chromium and pentacarbonyl(trimethylamine) molybdenum

Michael Findlater; Nicholas J. Hill; Alan H. Cowley

doi:10.1007/s10870-009-9626-9

Pentacarbonyl(trimethylamine)chromium and pentacarbonyl(trimethylamine) molybdenum

Michael Findlater, Nicholas J. Hill, Alan H. Cowley

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Pentacarbonyl(trimethylamine)chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P2 ₁/n, a = 6.8267(14) Å, b = 11.269(2) Å, c = 14.692(3) Å, β = 102.89(3)°, V = 1,101.8(4) Å³, Z = 4 for 1 and a = 6.949(5) Å, b = 11.362(5) Å, c = 14.927(5) Å, β = 102.639(5)°, V = 1,150.0(10) Å³, Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.

Original language	English
Pages (from-to)	64-66
Number of pages	3
Journal	Journal of Chemical Crystallography
Volume	40
Issue number	1
DOIs	https://doi.org/10.1007/s10870-009-9626-9
State	Published - Jan 2010

Keywords

Carbonyl
Chromium
Crystal structure
Molybdenum
Trimethylamine

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@article{4737adea43c242b68dce587f5502b386,

title = "Pentacarbonyl(trimethylamine)chromium and pentacarbonyl(trimethylamine) molybdenum",

abstract = "Pentacarbonyl(trimethylamine)chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P2 1/n, a = 6.8267(14) {\AA}, b = 11.269(2) {\AA}, c = 14.692(3) {\AA}, β = 102.89(3)°, V = 1,101.8(4) {\AA}3, Z = 4 for 1 and a = 6.949(5) {\AA}, b = 11.362(5) {\AA}, c = 14.927(5) {\AA}, β = 102.639(5)°, V = 1,150.0(10) {\AA}3, Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.",

keywords = "Carbonyl, Chromium, Crystal structure, Molybdenum, Trimethylamine",

author = "Michael Findlater and Hill, {Nicholas J.} and Cowley, {Alan H.}",

year = "2010",

month = jan,

doi = "10.1007/s10870-009-9626-9",

language = "English",

volume = "40",

pages = "64--66",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "1",

}

TY - JOUR

T1 - Pentacarbonyl(trimethylamine)chromium and pentacarbonyl(trimethylamine) molybdenum

AU - Findlater, Michael

AU - Hill, Nicholas J.

AU - Cowley, Alan H.

PY - 2010/1

Y1 - 2010/1

N2 - Pentacarbonyl(trimethylamine)chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P2 1/n, a = 6.8267(14) Å, b = 11.269(2) Å, c = 14.692(3) Å, β = 102.89(3)°, V = 1,101.8(4) Å3, Z = 4 for 1 and a = 6.949(5) Å, b = 11.362(5) Å, c = 14.927(5) Å, β = 102.639(5)°, V = 1,150.0(10) Å3, Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.

AB - Pentacarbonyl(trimethylamine)chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P2 1/n, a = 6.8267(14) Å, b = 11.269(2) Å, c = 14.692(3) Å, β = 102.89(3)°, V = 1,101.8(4) Å3, Z = 4 for 1 and a = 6.949(5) Å, b = 11.362(5) Å, c = 14.927(5) Å, β = 102.639(5)°, V = 1,150.0(10) Å3, Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.

KW - Carbonyl

KW - Chromium

KW - Crystal structure

KW - Molybdenum

KW - Trimethylamine

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U2 - 10.1007/s10870-009-9626-9

DO - 10.1007/s10870-009-9626-9

M3 - Article

AN - SCOPUS:73349084936

VL - 40

SP - 64

EP - 66

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

SN - 1074-1542

IS - 1

ER -