TY - JOUR
T1 - Pentacarbonyl(trimethylamine)chromium and pentacarbonyl(trimethylamine) molybdenum
AU - Findlater, Michael
AU - Hill, Nicholas J.
AU - Cowley, Alan H.
N1 - Funding Information:
Acknowledgments The authors are grateful to the Robert A. Welch Foundation (Grant F-0003) and the National Science Foundation (Grant CHE-0240008) for financial support.
PY - 2010/1
Y1 - 2010/1
N2 - Pentacarbonyl(trimethylamine)chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P2 1/n, a = 6.8267(14) Å, b = 11.269(2) Å, c = 14.692(3) Å, β = 102.89(3)°, V = 1,101.8(4) Å3, Z = 4 for 1 and a = 6.949(5) Å, b = 11.362(5) Å, c = 14.927(5) Å, β = 102.639(5)°, V = 1,150.0(10) Å3, Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.
AB - Pentacarbonyl(trimethylamine)chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P2 1/n, a = 6.8267(14) Å, b = 11.269(2) Å, c = 14.692(3) Å, β = 102.89(3)°, V = 1,101.8(4) Å3, Z = 4 for 1 and a = 6.949(5) Å, b = 11.362(5) Å, c = 14.927(5) Å, β = 102.639(5)°, V = 1,150.0(10) Å3, Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.
KW - Carbonyl
KW - Chromium
KW - Crystal structure
KW - Molybdenum
KW - Trimethylamine
UR - http://www.scopus.com/inward/record.url?scp=73349084936&partnerID=8YFLogxK
U2 - 10.1007/s10870-009-9626-9
DO - 10.1007/s10870-009-9626-9
M3 - Article
AN - SCOPUS:73349084936
VL - 40
SP - 64
EP - 66
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
SN - 1074-1542
IS - 1
ER -