Partial high-grade alteration of monazite using alkali-bearing fluids: Experiment and nature

Daniel E. Harlov, Callum J. Hetherington

Research output: Contribution to journalArticle

99 Scopus citations

Abstract

Recent advances in the dating of monazite using the electron microprobe indicate that ThSiO4- and/or CaTh(PO4)2- enriched intergrowths in monazite can give ages younger than the original monazite. The morphology of the intergrowths suggests that the original monazite grain has been partly altered by a fluid in which Th, Si, and Ca are mobile. This hypothesis has been tested in the piston-cylinder apparatus at 1000 MPa and 900 °C utilizing a natural, unzoned, Th- and Pb-bearing monazite-(Ce) and Na2Si2O5+H2O. During the experiment, a subset of the monazite grains acquired ThSiO4-enriched areas with sharp compositional boundaries devoid of Pb and show evidence of being a pseudomorphic partial replacement of the monazite rather than an overgrowth of the monazite. These experiments support the hypothesis that similar Th-enriched or Th-depleted patches with sharp compositional boundaries observed in natural monazite could be the result of fluid-induced alteration via coupled dissolution-reprecipitation. If so, such altered regions would yield information concerning the nature of the fluid responsible for their formation as well as allow for the dating of single or multiple metasomatic events assuming that all pre-existing radiogenic Pb is removed during alteration.

Original languageEnglish
Pages (from-to)1105-1108
Number of pages4
JournalAmerican Mineralogist
Volume95
Issue number7
DOIs
StatePublished - Jul 2010

Keywords

  • Alkali-bearing fluids
  • Dissolution-reprecipitation
  • Experimental petrology
  • Geochronology
  • High-grade metamorphism
  • Huttonite
  • Monazite
  • Th-U-Pb dating

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