TY - JOUR
T1 - Paramagnetic 1,3-dimetallacyclobutadienes of tungsten(VI)
T2 - 2,4-Bis(trimethylsilyl)-1,3-dihalogeno-1,1,3,3-tetrakis(trimethylsilylmethyl)-1, 3-ditungstacyclobutadienes
AU - Chisholm, Malcolm H.
AU - Heppert, Joseph A.
AU - Huffman, John C.
AU - Thornton, Peter
PY - 1985
Y1 - 1985
N2 - Addition of halogens, X2, to hydrocarbon solutions of [(Me 3SiCH2)2W(μ-CSiMe3)]2 leads to the novel paramagnetic WVI containing compounds [X(Me 3SiCH2)2W(μ-CSiMe3)] 2, where X = Cl, Br, and I, which contain tungsten atoms in a pseudo trigonal bipyramidal environment (X axial) joined along a common axial-equatorial edge by the μ-CSiMe3 ligands (W-W 2.75 Å).
AB - Addition of halogens, X2, to hydrocarbon solutions of [(Me 3SiCH2)2W(μ-CSiMe3)]2 leads to the novel paramagnetic WVI containing compounds [X(Me 3SiCH2)2W(μ-CSiMe3)] 2, where X = Cl, Br, and I, which contain tungsten atoms in a pseudo trigonal bipyramidal environment (X axial) joined along a common axial-equatorial edge by the μ-CSiMe3 ligands (W-W 2.75 Å).
UR - http://www.scopus.com/inward/record.url?scp=37049106081&partnerID=8YFLogxK
U2 - 10.1039/c39850001466
DO - 10.1039/c39850001466
M3 - Article
AN - SCOPUS:37049106081
SN - 0022-4936
SP - 1466
EP - 1467
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 21
ER -