Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters

Jinmin Miao, Ping Fang, Sahota Jagdeep, Haibo Ge

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters in the presence of potassium persulfate was performed under mild conditions. A number of benzoyl esters with a wide variety of substituents at different positions were efficiently synthesized with this method. Mechanism of the palladium-catalyzed decarboxylative carbonylation of aryltrifluoroborates was studied, and a radical-mediated Pd(ii)/Pd(iv) catalytic cycle was proposed.

Original languageEnglish
Pages (from-to)243-250
Number of pages8
JournalOrganic Chemistry Frontiers
Volume3
Issue number2
DOIs
StatePublished - Feb 2016

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