One-step synthesis of self-supporting tin oxide/graphene electrodes for lithium ion batteries

Arthur N. Gildea, Dan Wang, Gerardine G. Botte

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

A self-supporting binder-free tin oxide (SnO2) graphene nanocomposite electrode was synthesized through a novel one step solvothermal treatment of graphene oxide (GO) paper. To characterize this electrode X-ray Diffraction, Scanning Electron Microscopy, Atomic Force Microscopy, Raman spectroscopy, Energy-dispersive X-ray spectroscopy, cyclic voltammetry, and constant current galvanic cycling were performed. The solvothermal treatment simultaneously coats amorphous carbon and SnO2 nanoparticles onto the surface of GO paper, while reducing the GO nanosheets to graphene nanosheets (GNS). This creates a SnO2/GNS film that is flexible, free-standing, and can be used as the negative electrode in lithium ion batteries to deliver a reversible capacity of 400 mA h g−1 after repeated cycling.

Original languageEnglish
Pages (from-to)217-224
Number of pages8
JournalJournal of Applied Electrochemistry
Volume45
Issue number3
DOIs
StatePublished - Mar 2015

Keywords

  • Flexible electrode
  • Graphene
  • Self-supporting electrode
  • Solvothermal synthesis
  • Tin oxide composite

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