Observation of exceptionally strong binding of molecular hydrogen in a porous material: Formation of an η2-H2 complex in a Cu-exchanged ZSM-5 zeolite

Peter A. Georgiev; Alberto Albinati; Barbara L. Mojet; Jacques Ollivier; Juergen Eckert

doi:10.1021/ja072240l

Observation of exceptionally strong binding of molecular hydrogen in a porous material: Formation of an η²-H₂ complex in a Cu-exchanged ZSM-5 zeolite

Peter A. Georgiev, Alberto Albinati, Barbara L. Mojet, Jacques Ollivier, Juergen Eckert

Chemistry and Biochemistry

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Abstract

We have measured the rotational tunneling spectrum of a Cu-ZSM-5 zeolite after loading with H₂, by means of inelastic incoherent neutron scattering. The peaks at ±0.80 and ±1.73 cm^-1 unambiguously demonstrate the formation of a strongly bound Cu(η²-H₂) complex.

Original language	English
Pages (from-to)	8086-8087
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	26
DOIs	https://doi.org/10.1021/ja072240l
State	Published - Jul 4 2007

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10.1021/ja072240l

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title = "Observation of exceptionally strong binding of molecular hydrogen in a porous material: Formation of an η2-H2 complex in a Cu-exchanged ZSM-5 zeolite",

abstract = "We have measured the rotational tunneling spectrum of a Cu-ZSM-5 zeolite after loading with H2, by means of inelastic incoherent neutron scattering. The peaks at ±0.80 and ±1.73 cm-1 unambiguously demonstrate the formation of a strongly bound Cu(η2-H2) complex.",

author = "Georgiev, {Peter A.} and Alberto Albinati and Mojet, {Barbara L.} and Jacques Ollivier and Juergen Eckert",

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Observation of exceptionally strong binding of molecular hydrogen in a porous material: Formation of an η²-H₂ complex in a Cu-exchanged ZSM-5 zeolite. / Georgiev, Peter A.; Albinati, Alberto; Mojet, Barbara L. et al.
In: Journal of the American Chemical Society, Vol. 129, No. 26, 04.07.2007, p. 8086-8087.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Observation of exceptionally strong binding of molecular hydrogen in a porous material

T2 - Formation of an η2-H2 complex in a Cu-exchanged ZSM-5 zeolite

AU - Georgiev, Peter A.

AU - Albinati, Alberto

AU - Mojet, Barbara L.

AU - Ollivier, Jacques

AU - Eckert, Juergen

PY - 2007/7/4

Y1 - 2007/7/4

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AB - We have measured the rotational tunneling spectrum of a Cu-ZSM-5 zeolite after loading with H2, by means of inelastic incoherent neutron scattering. The peaks at ±0.80 and ±1.73 cm-1 unambiguously demonstrate the formation of a strongly bound Cu(η2-H2) complex.

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DO - 10.1021/ja072240l

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SN - 0002-7863

VL - 129

SP - 8086

EP - 8087

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 26

ER -

Observation of exceptionally strong binding of molecular hydrogen in a porous material: Formation of an η²-H₂ complex in a Cu-exchanged ZSM-5 zeolite

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