Novel imidazolination reaction of alkenes provides an easy access to new α,β-differentiated 1,2-vicinal diamines

Wei Pei; Cody Timmons; Xin Xu; Han Xun Wei; Guigen Li

doi:10.1039/b305149h

Novel imidazolination reaction of alkenes provides an easy access to new α,β-differentiated 1,2-vicinal diamines

Wei Pei, Cody Timmons, Xin Xu, Han Xun Wei, Guigen Li

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

α,β-Differentiated 1,2-vicinal diamines have been efficiently synthesized by using new electrophilic imidazolination reaction of alkenes. The hydrolysis of imidazolines was performed by treatment with 6 M HCl in THF at 70°C without epimerization. Eight examples were examined to give good to excellent yields (87-96%).

Original language	English
Pages (from-to)	2919-2921
Number of pages	3
Journal	Organic and Biomolecular Chemistry
Volume	1
Issue number	16
DOIs	https://doi.org/10.1039/b305149h
State	Published - Aug 21 2003

Access to Document

10.1039/b305149h

Cite this

@article{c5bbe3e9612f470ca78d62ea1e141df4,

title = "Novel imidazolination reaction of alkenes provides an easy access to new α,β-differentiated 1,2-vicinal diamines",

abstract = "α,β-Differentiated 1,2-vicinal diamines have been efficiently synthesized by using new electrophilic imidazolination reaction of alkenes. The hydrolysis of imidazolines was performed by treatment with 6 M HCl in THF at 70°C without epimerization. Eight examples were examined to give good to excellent yields (87-96%).",

author = "Wei Pei and Cody Timmons and Xin Xu and Wei, {Han Xun} and Guigen Li",

year = "2003",

month = aug,

day = "21",

doi = "10.1039/b305149h",

language = "English",

volume = "1",

pages = "2919--2921",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

number = "16",

}

TY - JOUR

T1 - Novel imidazolination reaction of alkenes provides an easy access to new α,β-differentiated 1,2-vicinal diamines

AU - Pei, Wei

AU - Timmons, Cody

AU - Xu, Xin

AU - Wei, Han Xun

AU - Li, Guigen

PY - 2003/8/21

Y1 - 2003/8/21

N2 - α,β-Differentiated 1,2-vicinal diamines have been efficiently synthesized by using new electrophilic imidazolination reaction of alkenes. The hydrolysis of imidazolines was performed by treatment with 6 M HCl in THF at 70°C without epimerization. Eight examples were examined to give good to excellent yields (87-96%).

AB - α,β-Differentiated 1,2-vicinal diamines have been efficiently synthesized by using new electrophilic imidazolination reaction of alkenes. The hydrolysis of imidazolines was performed by treatment with 6 M HCl in THF at 70°C without epimerization. Eight examples were examined to give good to excellent yields (87-96%).

UR - http://www.scopus.com/inward/record.url?scp=0041817834&partnerID=8YFLogxK

U2 - 10.1039/b305149h

DO - 10.1039/b305149h

M3 - Article

C2 - 12968342

AN - SCOPUS:0041817834

VL - 1

SP - 2919

EP - 2921

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

IS - 16

ER -

Novel imidazolination reaction of alkenes provides an easy access to new α,β-differentiated 1,2-vicinal diamines

Abstract

Access to Document

Other files and links

Fingerprint

Cite this