Abstract
Several Rh(I), Ir(III), and Pt(II) complexes of the chiral P,S-bidentate ligand 2 have been prepared and characterized. Detailed two-dimensional NMR studies show that (i) the boat-type chelate ring and the stereogenic sulfur center can invert rapidly at ambient temperature and (ii) the sulfur donor may dissociate, essentially destroying the chiral pocket. The solid-state structure of [Pt(η3-C3H5)(2)]PF6 (3) has been determined and the sulfur substituent shown to have an axial orientation. The six-membered chelate ring takes up a boatlike conformation. As shown by an X-ray diffraction study for 3, and via incoherent inelastic neutron scattering (IINS) measurements for the Pd analog, 4, the OH group is remote from the metal atom.
Original language | English |
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Pages (from-to) | 579-590 |
Number of pages | 12 |
Journal | Organometallics |
Volume | 16 |
Issue number | 4 |
DOIs | |
State | Published - 1997 |