TY - JOUR
T1 - Multi-layer 3D chirality
T2 - new synthesis, AIE and computational studies
AU - Liu, Yangxue
AU - Wu, Guanzhao
AU - Yang, Zhen
AU - Rouh, Hossein
AU - Katakam, Nandakumar
AU - Ahmed, Sultan
AU - Unruh, Daniel
AU - Cui, Zhonghua
AU - Lischka, Hans
AU - Li, Guigen
N1 - Publisher Copyright:
© 2020, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - New synthesis of multi-layer 3D chiral molecules has been developed under novel conditions to give better outcomes. The aggregation-induced emission (AIE), UV irradiation/excitation, charge transfer (CT) and local excited (LE) ππ* transitions have been investigated on a representative individual enantiomer of pseudo C2 asymmetry which was made possibly by differentiating moieties on phosphorous on N-phosphonyl ring of chiral sandwich framework. Meanwhile, a new tandem C-N/C-C coupling reaction was unexpectedly rendered providing a novel access to special benzo[a]carbazoles.
AB - New synthesis of multi-layer 3D chiral molecules has been developed under novel conditions to give better outcomes. The aggregation-induced emission (AIE), UV irradiation/excitation, charge transfer (CT) and local excited (LE) ππ* transitions have been investigated on a representative individual enantiomer of pseudo C2 asymmetry which was made possibly by differentiating moieties on phosphorous on N-phosphonyl ring of chiral sandwich framework. Meanwhile, a new tandem C-N/C-C coupling reaction was unexpectedly rendered providing a novel access to special benzo[a]carbazoles.
KW - aggregation-induced emission (AIE)
KW - architecture chirality
KW - charge transfer (CT)
KW - multi-layer 3D chirality
KW - organo sandwich chirality
UR - http://www.scopus.com/inward/record.url?scp=85082920788&partnerID=8YFLogxK
U2 - 10.1007/s11426-019-9711-x
DO - 10.1007/s11426-019-9711-x
M3 - Article
AN - SCOPUS:85082920788
VL - 63
SP - 692
EP - 698
JO - Science China Chemistry
JF - Science China Chemistry
SN - 1674-7291
IS - 5
ER -